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Journal Articles

Electrochemical measurements in various environments; Corrosion monitoring of carbon steel in deep underground environment

Taniguchi, Naoki; Nakayama, Masashi

Zairyo To Kankyo, 67(12), p.487 - 494, 2018/12

This article describes the current status of corrosion monitoring methods and examples of the measurement under deep underground environments for carbon steel overpacks for high-level radioactive waste disposal. Based on the studies on corrosion monitoring using AC Impedance technique, some of the typical measurement systems such as the electrodes arrangement are introduced. In-situ corrosion monitoring in engineering scale test is also being attempted using a deep underground research facility, and the measurement method and results are presented in this article.

JAEA Reports

The In-situ experiment for overpack corrosion at Horonobe Underground Research Laboratory; Production and setting simulated overpack, buffer material blocks and heater

Nakayama, Masashi

JAEA-Technology 2018-006, 43 Pages, 2018/08

JAEA-Technology-2018-006.pdf:5.32MB
JAEA-Technology-2018-006-appendix(CD-ROM).zip:29.19MB

The Horonobe URL Project has being pursued by JAEA to enhance the reliability of relevant disposal technologies through investigations of the deep geological environment within the host sedimentary formation at Horonobe, Hokkaido. The URL Project proceeds in 3 overlapping phases, "Phase I: Surface-based investigations", "Phase II: Investigations during tunnel excavation" and "Phase III: Investigations in the underground facilities", over a period of around 20 years. The OP corrosion test was prepared from 2013 FY at Niche No.3, and heating by electric heater in simulated overpack started in November, 2014. The objective of the test is acquiring data concerned with corrosion of carbon steel OP. These data will be used in order to confirm the performance of engineered barrier system. In the OP corrosion test, the diameter of simulated OP and buffer material are 100 mm and 300 mm, respectively. Concrete support using low alkaline cement was used in order to investigate the effect of cementitious materials to OP corrosion behavior. We will measure corrosion potential of carbon steel, natural potential, pH in buffer material for several years. In this report, we describe how to make simulated OP and buffer material blocks, and set sensors, and so on.

Journal Articles

Characterization of Fe-montmorillonite; A Simulant of buffer materials accommodating overpack corrosion product

Kozai, Naofumi; Adachi, Yoshifusa*; Kawamura, Sachi*; Inada, Koichi*; Kozaki, Tamotsu*; Sato, Seichi*; Ohashi, Hiroshi*; Onuki, Toshihiko; Bamba, Tsunetaka

Journal of Nuclear Science and Technology, 38(12), p.1141 - 1143, 2001/12

This study briefly reports characteristics of Fe-montmorillonite. Fe-montmorillonite was used as a simulant of buffer material in which corrosion products of carbon steel overpack, Fe$$^{2+}$$, were diffused. We have found that this clay retains Se(VI) for which natural montmorillonite, such as Na+-type and Ca$$^{2+}$$-type, has little retentivity.

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